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This is indicated by the left-most segment of the dashed line The minor contributions of 2' to the correlations are here neglected In view of the uncertainty associated with any generalized correlation, deviations of no more than 2% in 2 are not significant ' The relative simplicity of the generalized virial-coefficient correlation does much to recommend it Moreover, temperatures and pressures of many chemical-processing operations lie within the region where it does not deviate by a significant amount from the compressibilityfactor correlation Like the parent correlation, it is most accurate for nonpolar species and least accurate for highly polar and associating molecules The question often arises as to when the ideal-gas equation may be used as a reasonable approximation to reality Figure 316 can serve as a guide

Traditional cameras rely on good old-fashioned film But what is film, really It s just a strip of plastic that has been coated with a light-sensitive chemical The chemical soup on the film is loaded with grains of silver halide When exposed to light, the silver halide reacts, and that is the essence of photography The longer the film is exposed to light, the more the silver is affected

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Building SQL statements by hand involves a lot of string manipulation, plus conditional processing for those times when data may be missing. For instance, if you want to store a text value in the database, you have to prepare it for use by a SQL statement (special processing for single quote marks), but if the text value is zerolength, you pass the word NULL in the statement instead. All of this data preparation can clog up your code, so why not centralize it The eight routines in this section either prepare data for use in SQL statements, or adjust retrieved data for use in the application.

Determine the molar volume of n-butane at 510K and 25bar by each of the following: (a) The ideal-gas equation

Although the molar volumes of liquids can be calculated by means of generalized cubic equations of state, the results are often not of high accuracy However, the LeeIKesler correlation includes data for subcooled liquids, and Fig 314 illustrates curves for both liquids and gases Values for both phases are provided in Tables El through E4 Recall, however, that this correlation is most suitable for nonpolar and slightly polar fluids In addition, generalized equations are available for the estimation of molar volumes of saturated liquids The simplest equation, proposed by ~ackett,"is an example:

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Takes the numeric code associated with a selected item in a ComboBox control and returns it as a string. If no item is selected or the value is 1, the routine returns NULL.

The only data required are the critical constants, given in App B Results are usually accurate to 1 or 2% Lydersen, Greenkorn, and ~ o u g e n developed a two-parameter corresponding-states '~ correlation for estimation of liquid volumes It provides a correlation of reduced density p, as a function of reduced temperature and pressure By definition,

1 8 ~ G Rackett, J Chem Eng Data, vol 15, pp 514-517, 1970; see also C F Spencer and S B Adler, ibid, vol 23, pp 82-89, 1978, for a review of available equations 1 9 ~ L Lydersen, R A Greenkorn, and 0 A Hougen, "Generalized Thermodynamic Properties of Pure Fluids," UnivWisconsin, Eng Expt Sta Rept 4, 1955

where p, is the density at the critical point The generalized correlation is shown by Fig 317 This figure may be used directly with Eq (364) for determination of liquid volumes if the value of the critical volume is known A better procedure is to make use of a single known liquid volume (state 1) by the identity,

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FIGURE 12-1

This method gives good results and requires only experimental data that are usually available Figure 317 makes clear the increasing effects of both temperature and pressure on liquid density as the critical point is approached Correlations for the molar densities as functions of temperature are given for many pure liquids by Daubert and coworkers20

For ammonia at 310 K(3685%), estimate the density of:

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